Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol.

نویسندگان

  • Catalina Ferrer
  • Peter Fodran
  • Santiago Barroso
  • Robert Gibson
  • Ellen C Hopmans
  • Jaap Sinninghe Damsté
  • Stefan Schouten
  • Adriaan J Minnaard
چکیده

An efficient asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol is presented employing catalytic asymmetric conjugate addition and catalytic epoxide ring opening as the key steps. Their occurrence in deep sea hydrothermal vents has been confirmed by chromatographic comparison with natural samples.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 11 15  شماره 

صفحات  -

تاریخ انتشار 2013